1264175-89-4Relevant articles and documents
18O assisted analysis of a γ,δ-epoxyketone cyclization: Synthesis of the C16-C28 fragment of ammocidin D
Chau, Stephen T.,Hayakawa, Yoichi,Sulikowski, Gary A.
, p. 756 - 759 (2011/04/24)
The C16-C28 fragment common to the cytotoxic macrolide ammocidin D has been prepared by a stereospecific 5-exo closure of a γ,δ-epoxyketone followed by a rearrangement to a pyran acetal. The reaction pathway was traced by 18O labeling of the ke