1264833-16-0

Basic information

• Product Name: C₁₃H₁₈O₃
• Synonyms: C₁₃H₁₈O₃
• CAS NO: 1264833-16-0
• Molecular Weight: 222.284
• Mol File: 1264833-16-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₈O₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₈O₃(1264833-16-0)
• EPA Substance Registry System: C₁₃H₁₈O₃(1264833-16-0)

Safety Data

• Hazardous Substances Data: 1264833-16-0(Hazardous Substances Data)

Upstream product

• 138517-53-0 5-(2,2,5-trimethyl-1,3-dioxane)carbaldehyde 
• 98-88-4 benzoyl chloride 
• 99115-97-6 2-methyl-2-vinyl-propane-1,3-diol 
• 77-84-9 2-ethyl-2-methyl-1,3-propanediol 
• 1264833-23-9 C₁₃H₁₄Br₂O₃ 
• 1264833-22-8 C₁₃H₁₆O₃ 

Relevant articles and documents

Asymmetric synthesis of all-carbon quaternary stereocenters via desymmetrization of 2,2-disubstituted 1,3-propanediols

A novel enantioselective desymmetrization of 2,2-disubstituted 1,3-propanediols has been established to generate all-carbon quaternary stereocenters, which has been implemented with BzCl and Et3N in the presence of Pybox(6)-CuCl2 complex in CH2Cl2 or PhMe at 78°C. While all the cyanide-comprising diols were desymmetrized with superb enantioselectivity (higher than 98% ee), the stereoinduction of the other substrates greatly depends on the size difference between the two substituents at the 2-position. When the size difference becomes larger, the corresponding substrates tend to engender enhanced enantioselectivity (up to 99% ee).