1267964-65-7Relevant articles and documents
Aryne-mediated fluorination: Synthesis of fluorinated biaryls via a sequential desilylation-halide elimination-fluoride addition process
Diemer, Vincent,Garcia, Juan Sanz,Leroux, Frédéric R.,Colobert, Fran?oise
experimental part, p. 146 - 155 (2012/02/15)
An unusual aryne-mediated fluorination of aromatic ring systems during the desilylation of ortho-bromo-biphenyl-trimethylsilanes with tetrabutylammonium fluoride (TBAF) is described. In situ formation of an aryne and addition of fluoride affords fluorinat