126864-13-9

Basic information

• Product Name: C₂₇H₂₇NP⁽¹⁺⁾*I^(1-)
• Synonyms: C₂₇H₂₇NP⁽¹⁺⁾*I^(1-)
• CAS NO: 126864-13-9
• Molecular Weight: 523.396
• Mol File: 126864-13-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₂₇H₂₇NP⁽¹⁺⁾*I^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₂₇NP⁽¹⁺⁾*I^(1-)(126864-13-9)
• EPA Substance Registry System: C₂₇H₂₇NP⁽¹⁺⁾*I^(1-)(126864-13-9)

Safety Data

• Hazardous Substances Data: 126864-13-9(Hazardous Substances Data)

Upstream product

• 603-35-0 triphenylphosphine 
• 15729-44-9 amino(triphenyl)phosphonium chloride 
• 13916-35-3 lithium triphenylphosphonium azayldiide 
• 15931-69-8 bromure de triphenyl aminophosphonium 
• 47182-04-7 ethyl-triphenylphosphoranyliden-amine 
• 620-05-3 iodomethylbenzene 
• 124316-00-3 1-<<(Triphenylphosphoranylidene)amino>methyl>benzotriazole 
• 75-03-6 ethyl iodide 
• 52826-45-6 (benzylimino)triphenylphosphorane 
• 100-39-0 benzyl bromide 

Downstream Products

• 14321-27-8 N-ethylbenzylamine 

Relevant articles and documents

PHOSPHONIUM DIAZA-DIYLIDS AND AZA-YLDIID AS NEW AND EFFICIENT REAGENTS FOR PRIMARY AND SECONDARY AMINES SYNTHESIS

Metallated aminophosphonium ylids, diaza-diylids and aza-yldiid, are investigated as reagents for primary and secondary amines synthesis.

Alkylation et acylation de la triphenylphosphinimine N-lithiee

A new synthetic approach to primary and secondary amines using N-lithiated triphenylphosphinimine is reported.This key reagent, accessible in two steps from dibromortiphenylphosphorane and ammonia, when treated with electrophiles yields N-substituted triphenylphosphinimine derivatives.These can react to give N-mono or disubstituted triphenylphosphonium salts which upon hydrolysis lead to the corresponding primary and secondary amines.