1268823-04-6Relevant articles and documents
Synthesis and characterization of amino-NHC coinage metal complexes and application for C-H activation of caffeine
Huang, Hsuan-Jui,Lee, Wei-Chih,Yap, Glenn P.A.,Ong, Tiow-Gan
, p. 64 - 73 (2014/05/06)
This paper describes the synthesis and characterization of silver, copper and gold complexes supported by several amino-NHC ligands with different amino side arms. The transmetallation process using silver-NHC complexes can be used to prepare amino-NHC copper and gold complexes easily in high yield. In addition, the catalytic activities of copper complexes are examined for arylation of caffeine via C-H bond activation.