1269141-74-3

Basic information

• Product Name: (1R,4R,5R,6R)-6-(3-methoxybenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate
• Synonyms: (1R,4R,5R,6R)-6-(3-methoxybenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate
• CAS NO: 1269141-74-3
• Molecular Weight: 440.548
• Mol File: 1269141-74-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,4R,5R,6R)-6-(3-methoxybenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R,5R,6R)-6-(3-methoxybenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate(1269141-74-3)
• EPA Substance Registry System: (1R,4R,5R,6R)-6-(3-methoxybenzyl)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane trifluoromethanesulfonate(1269141-74-3)

Safety Data

• Hazardous Substances Data: 1269141-74-3(Hazardous Substances Data)

Upstream product

• 33454-82-9 lithium trifluoromethanesulfonate 
• 874-98-6 1-bromomethyl-3-methoxybenzene 
• 5718-75-2 (1R,4R,5R)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane 

Downstream Products

• 1269142-01-9 C₂₄H₂₃NO₃S 
• 1269141-90-3 (2R,3R)-2-((E)-3-methoxystyryl)-3-phenyl-1-tosylaziridine 

Relevant articles and documents

Stereospecific ring expansion of chiral vinyl aziridines

In this report, it is demonstrated that chiral vinyl aziridines can be stereospecifically ring expanded. This synthetic approach allows controlled access to chiral 2,5-cis-or 2,5-trans-3-pyrroline products from starting materials with the appropriate aziridine geometry. Twenty three ring expansion examples, most of which feature a stereospecific cyclization, are presented.(Figure Presented)