126957-58-2

Basic information

• Product Name: S-(1-Methyl-2-pyridyliden)-N-phenylsulfonylsulfimid
• Synonyms: S-(1-Methyl-2-pyridyliden)-N-phenylsulfonylsulfimid
• CAS NO: 126957-58-2
• Molecular Weight: 280.371
• Mol File: 126957-58-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: S-(1-Methyl-2-pyridyliden)-N-phenylsulfonylsulfimid(CAS DataBase Reference)
• NIST Chemistry Reference: S-(1-Methyl-2-pyridyliden)-N-phenylsulfonylsulfimid(126957-58-2)
• EPA Substance Registry System: S-(1-Methyl-2-pyridyliden)-N-phenylsulfonylsulfimid(126957-58-2)

Safety Data

• Hazardous Substances Data: 126957-58-2(Hazardous Substances Data)

Upstream product

• 2044-27-1 1-methyl-2-pyridinethione 
• 127-52-6 chloramine-B 

Downstream Products

• 135274-27-0 N-phenylsulfonyl-1-methyl-2-pyridiniumsulfonamidate 
• 52814-22-9 N-(1-Methyl-2-pyridyliden)benzolsulfonamid 

Relevant articles and documents

REAKTIONEN VON THIOXOHETEROCYCLEN MIT N-CHLORAMIDEN II. N-SUBSTITUIERTE 2- ODER 4-THIOPYRIDONE UND NATRIUM-N-CHLORBENZOLSULFONAMIDE

N-Substituted 2- and 4-pyridinethiones A react with sodium-N-chlorobenzenesulfonamides 1 to N-phenylsulfonyl-S-pyridylidenesulfimides B, N,N'-bis(phenylsulfonyl)-S-pyridiniosulfodiimidates C and N-pyridylidenebenzenesulfonamides D.The constitution of the new pyridiniosulfodiimidates C is proved by X-ray crystal structure of one compound C and by 1H-NMR spectra of all 1-methylpyridinio-compounds C, which have a downfield shift for the N-methyl-δ-values.Formation, stabilities, IR-, 1H-NMR-spectra and bond systems of A-D are discussed.Key words: Pyridinethiones; sodium N-chlorobenzenesulfonamides; N-phenylsulfonyl-S-pyridylidenesulfimides; N,N'-bis(phenylsulfonyl)-S-pyridiniosulfodiimidates; N-pyridylidenebenzenesulfonamides; polarity of sulfur bonds.