127072-92-8Relevant articles and documents
Simplified deoxypropionate acyl chains for mycobacterium tuberculosis sulfoglycolipid analogues: Chain length is essential for high antigenicity
Gau, Benjamin,Lemetais, Aurelie,Lepore, Marco,Garcia-Alles, Luis Fernando,Bourdreux, Yann,Mori, Lucia,Gilleron, Martine,De Libero, Gennaro,Puzo, Germain,Beau, Jean-Marie,Prandi, Jacques
, p. 2413 - 2417 (2014/01/06)
The longer, the better: Increasing the lengths of the 1,3-methyl-branched fatty acyl chain units in mycobacterial diacylated sulfoglycolipid (Acyl 2SGL) analogues led to dramatic improvements in their antigenic properties and gave products more
TMSOTf-catalyzed silylation: Streamlined regioselective one-pot protection and acetylation of carbohydrates
Joseph, A. Abragam,Verma, Ved Prakash,Liu, Xin-Yi,Wu, Chia-Hui,Dhurandhare, Vijay M.,Wang, Cheng-Chung
, p. 744 - 753 (2012/03/11)
A highly efficient TMSOTf-catalyzed HMDS silylation of sugars, which can easily be integrated with subsequent reactions in one-pot fashion, has been developed. Its usefulness was demonstrated by applications to streamlined regioselective one-pot protection and nonenzymatic acetylation of unprotected sugars. Monosaccharide and trehalose building blocks with orthogonally well-differentiated hydroxy groups were efficiently prepared starting with free sugars in one-pot fashion without the need for prior per-O-silylation. Regioselectively protected and acetylated building blocks were prepared directly from unprotected sugars in a one-pot manner involving up to five TMSOTf-catalyzed reactions, including a new TMSOTf-catalyzed silylation of carbohydrates. Copyright
Synthesis of biologically potent α1 →2-linked disaccharide derivatives via regioselective one-pot protection - Glycosylation
Wang, Cheng-Chung,Lee, Jinq-Chyi,Luo, Shun-Yuan,Fan, Hsin-Fang,Pai, Chin-Ling,Yang, Wei-Chieh,Lu, Ng-Dai,Hung, Shang-Cheng
, p. 2360 - 2362 (2007/10/03)
A highly regioselective benzyl and allyl protection of D-hexopyranosides allows their application in the synthesis of biologically potent α1→2 linked disaccharide derivatives by means of a regioselective one-pot protection-glycosylation (see scheme).