127118-32-5Relevant articles and documents
A PREDOMINATELY ANTI-STEREOSELECTIVE CHIRAL METAL DIRECTED ALDOL CONDENSATION WITH AROMATIC ALDEHYDES
Pridgen, Lendon N.,Abdel-Magid, A.,Lantos, I.
, p. 5539 - 5542 (2007/10/02)
Chiral haloacetyl oxazolidinones were reacted with aromatic aldehydes via their kinetically generated Z-enolates to yield predominately anti aldol adducts.The reaction is postulated to proceed thru a boat-like transition state.A unique reversal of chirality was observed in using stannous enolates.