127214-51-1

Basic information

• Product Name: methyl 2,3,6-Tri-O-Benzyl-4-Deoxy-4-Formyl-α-D-Gluco-Pyranoside
• Synonyms: methyl 2,3,6-Tri-O-Benzyl-4-Deoxy-4-Formyl-α-D-Gluco-Pyranoside
• CAS NO: 127214-51-1
• Molecular Weight: 476.569
• Mol File: 127214-51-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 2,3,6-Tri-O-Benzyl-4-Deoxy-4-Formyl-α-D-Gluco-Pyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,6-Tri-O-Benzyl-4-Deoxy-4-Formyl-α-D-Gluco-Pyranoside(127214-51-1)
• EPA Substance Registry System: methyl 2,3,6-Tri-O-Benzyl-4-Deoxy-4-Formyl-α-D-Gluco-Pyranoside(127214-51-1)

Safety Data

• Hazardous Substances Data: 127214-51-1(Hazardous Substances Data)

Upstream product

• 127214-50-0 methyl 2,3,6-tri-O-benzyl-4-cyano-4-deoxy-α-D-glucopyranoside 
• 127924-50-9 methyl 2,3,6-tri-O-benzyl-4-deoxy-4-C-(hydroxymethyl)-α-D-galactopyranoside 
• 139070-96-5 Methyl 2,3,6-Tri-O-benzyl-4-deoxy-4-C-(methylene)-α-D-xylo-hexopyranoside 
• 98807-61-5 1-O-methyl-2,3,6-tri-O-benzyl-4-keto-α-D-glucopyranoside 
• 19488-48-3 methyl O-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 139070-99-8 Methyl 2,3,6-Tri-O-benzyl-4-deoxy-4-C-(formyl)-α-D-galactopyranoside 
• 3396-99-4 methyl α-D-galactopyranoside 
• 127924-45-2 (2R,3S,4R,5R,6S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-methoxy-3-trimethylsilanylethynyl-tetrahydro-pyran-3-ol 
• 127924-41-8 (2R,4R,5R,6S)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-methoxy-dihydro-pyran-3-one 
• 100-39-0 benzyl bromide 
• 492-62-6 alpha-D-glucopyranose 
• 127243-54-3 ((2S,4S,5R,6S)-4,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yl)-methanol 

Downstream Products

• 127243-54-3 METHYL 2,3,6-TRI-O-BENZYL-4-DEOXY-4-HYDROXYMETHYL-α-D-GLUCO-PYRANOSIDE 
• 139071-07-1 Methyl 2',6-Anhydro-2,3-di-O-benzyl-4-deoxy-4-C-(3',4',5',7'-tetra-O-benzyl-1'-deoxy-α-D-gluco-2-heptulopyranos-1'-yl)-α-D-glucopyranoside 
• 139071-04-8 Methyl 2,3,6-Tri-O-benzyl-4-deoxy-4-C-(3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulopyranos-1-yl)-α-D-glucopyranoside 
• 139071-05-9 Methyl 4-C-(6-O-Acetyl-3,4,5,7-tetra-O-benzyl-2-heptulo-D-glucos-1-yl)-2,3,6-tri-O-benzyl-4-deoxy-α-D-glucopyranoside 
• 127924-52-1 (3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-2-((2S,3R,4S,5R,6S)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-ylethynyl)-tetrahydro-pyran-2-ol 
• 127924-53-2 C₆₄H₆₆O₁₀ 
• 138459-11-7 methyl 2,3,6-tri-O-benzyl-4-deoxy-4-(iodomethyl)-α-D-glucopyranoside 
• 127924-51-0 (2S,3R,4S,5R,6S)-3,4-Bis-benzyloxy-6-benzyloxymethyl-5-(2,2-dibromo-vinyl)-2-methoxy-tetrahydro-pyran 

Relevant articles and documents

Synthesis of an 1′-azasugar analogue of maltose

Methyl 1′-azamaltoside (3) was synthesised from levoglucosane and D-galactose in a 16 step synthesis. Methyl 1′-azamaltoside (3) was found to inhibit glucoamylase with Ki of 0.63 μM.

Spiroketal Synthesis. - A Case of Intramolecular Glycoside Bond Formation

From 4-O-unsubstituted glucose derivatives 1a, b the 4-hydroxymethyl-substituted glucose derivatives 9a, b were obtained via oxidation to the ketone, Wittig reaction with methylenetriphenylphosphorane, borane addition, and subsequent oxidation to yield th