127258-28-0

Basic information

• Product Name: Aluminum, (benzenemethaniminato)bis(2-methylpropyl)-
• CAS NO: 127258-28-0
• Molecular Formula: C15H24AlN
• Molecular Weight: 245.344
• Mol File: 127258-28-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Aluminum, (benzenemethaniminato)bis(2-methylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Aluminum, (benzenemethaniminato)bis(2-methylpropyl)-(127258-28-0)
• EPA Substance Registry System: Aluminum, (benzenemethaniminato)bis(2-methylpropyl)-(127258-28-0)

Safety Data

• Hazardous Substances Data: 127258-28-0(Hazardous Substances Data)

Upstream product

• 1191-15-7 diisobutylaluminium hydride 
• 100-47-0 benzonitrile 

Downstream Products

• 1217456-02-4 C₁₅H₂₁NO₄ 

Relevant articles and documents

Conversion of nitriles to 1-aminophosphonic acids and preparation of phosphahomocysteines of high enantiomeric excess

A variety of nitriles was reduced to diisobutylaluminum salts of aldimines, to which diisopropyl phosphite was added. The corresponding 1-aminophosphonates were either deprotected to give racemic 1-aminophosphonic acids or reacted with Boc2O to yield N-Boc-protected 1-aminophosphonates. The enantiomers of 2-benzylthio-1-(t-butoxycarbonylamino)propylphosphonate were obtained from the racemate by chiral HPLC and converted to phosphonic acid analogs of (R)- and (S)-homocysteine, (R)- and (S)-2-aminobutyric acid and (S)-methionine, all of ee >97% as determined by chiral HPLC.

Enantioselective synthesis of optically active homoallylamines by allylboration of N-diisobutylaluminum imines

Diisobutylaluminum hydride (DIBAL-H) reduces nitriles to give N-diisobutylaluminum imines, which were asymmetrically allylated with chirally modified allylboron reagents. The corresponding chiral primary homoallylamines were obtained with up to 87% ee.