127269-25-4

Basic information

• Product Name: Benzoyl fluoride, 3,4-difluoro- (9CI)
• Synonyms: Benzoyl fluoride, 3,4-difluoro- (9CI)
• CAS NO: 127269-25-4
• Molecular Formula: C₇H₃F₃O
• Molecular Weight: 160.0933296
• Product Categories: HALIDE;ACIDHALIDE
• Mol File: 127269-25-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzoyl fluoride, 3,4-difluoro- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoyl fluoride, 3,4-difluoro- (9CI)(127269-25-4)
• EPA Substance Registry System: Benzoyl fluoride, 3,4-difluoro- (9CI)(127269-25-4)

Safety Data

• Hazardous Substances Data: 127269-25-4(Hazardous Substances Data)

Upstream product

• 127986-80-5 4-fluoro-3-(fluorosulfonyl)benzoyl fluoride 
• 3024-72-4 3,4-dichlorobenzoyl chloride 
• 5216-25-1 4-chlorotrichloromethylbenzene 
• 2494-79-3 4-chloro-3-(chlorosulfonyl)benzoic acid 
• 62574-66-7 3-chlorosulfonyl-4-chlorobenzoyl chloride 

Downstream Products

• 455-86-7 3,4-Difluorobenzoic acid 
• 85118-04-3 (3,4-difluoro-phenyl)-amide 
• 64248-62-0 3,4-Difluorobenzonitrile 
• 76903-88-3 3,4-difluorobenzoyl chloride 
• 3863-11-4 3,4-difluoroaniline 

Relevant articles and documents

General and Highly Efficient Syntheses of m-Fluoro Arenes Using Potassium Fluoride-Exchange Method

Tetraphenylphosphonium bromide was found to be a suitable catalyst for the reaction of m-nitroaryl derivatives carrying cyano, nitro, chlorocarbonyl, trifluoromethyl, and chlorosulfonyl groups with potassium fluoride in the presence of a stoichiometric amount of phthaloyl dichloride, giving the corresponding m-fluoro aromatic derivatives in good yields.The catalyst was also found to be efficient for the fluorodesulfonylation of m-(fluorosulfonyl)aryl derivatives to afford m-fluoro arenes by the use of a reaction-distillation technique.

Tetraphenylphosphonium Bromide Catalyzed Fluorodenitrations and Fluorodesulfonylations. Efficient Syntheses of m-Fluoroaromatic Compounds

Meta-fluoroaromatic compounds were effectively synthesized from m-nitroaromatic or m-fluorosulfonylaromatic compounds by replacement reaction with potassium fluoride in the presence of a catalytic amount of tetraphenylphosphonium bromide.