127395-13-5

Basic information

• Product Name: 2-chloro-1,3-ditosylate propane
• CAS NO: 127395-13-5
• Molecular Weight: 418.919
• Mol File: 127395-13-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-chloro-1,3-ditosylate propane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-1,3-ditosylate propane(127395-13-5)
• EPA Substance Registry System: 2-chloro-1,3-ditosylate propane(127395-13-5)

Safety Data

• Hazardous Substances Data: 127395-13-5(Hazardous Substances Data)

Upstream product

• 497-04-1 2-chloro-propane-1,3-diol 

Relevant articles and documents

Repulsive gauche conformational effect. Analysis of seven-membered rings containing endo and exo sulfur atoms

The so-called repulsive gauche conformational effect associated with sulfur is investigated through a study of 3-methylthio-1,5-benzodioxepin (1) and 3-methylthio-1-benzoxepin (2), together with 3-fluoro- and 3-chloro-1,5-benzodithiepins (3 and 4), by 13C and 1H dynamic nuclear magnetic resonance methods.The results show that, while compounds 2, 3, and 4 exhibit a large amount of the Ce conformation, the TB form predominates for compound 1.Intramolecular stereoelectronic ?-?* orbital interactions are analyzed, together with several other factors (steric, electrostatic, and solvation), to explain the observed conformational behaviour.