127665-52-5

Basic information

• Product Name: 3-Methyl-10,11-dihydro-9H-phenanthro[4,3-b]furan-4,5,8-trione
• Synonyms: 3-Methyl-10,11-dihydro-9H-phenanthro[4,3-b]furan-4,5,8-trione
• CAS NO: 127665-52-5
• Molecular Weight: 280.28
• Mol File: 127665-52-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Methyl-10,11-dihydro-9H-phenanthro[4,3-b]furan-4,5,8-trione(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methyl-10,11-dihydro-9H-phenanthro[4,3-b]furan-4,5,8-trione(127665-52-5)
• EPA Substance Registry System: 3-Methyl-10,11-dihydro-9H-phenanthro[4,3-b]furan-4,5,8-trione(127665-52-5)

Safety Data

• Hazardous Substances Data: 127665-52-5(Hazardous Substances Data)

Upstream product

• 4746-96-7 1,4-dioxaspiro[4.5]decan-6-one 
• 118949-96-5 2-vinylcyclohex-2-en-1-one ethylene glycol ketal 
• 113297-21-5 4,5-dihydro-3-methylbenzo[1,2-b]furan-4,5-dione 

Relevant articles and documents

Ultrasound-Promoted Cycloadditions in the Synthesis of Salvia miltiorrhiza Abietanoid o-Quinones

The ultrasound-promoted Diels-Alder reaction of 3-methyl-4,5-benzofurandione with appropriately substituted vinylcyclohexenes has led to the synthesis of tanshinone IIA, nortanshinone, tanshindiol B, methyl tanshinonate, and tanshinone IIB, biologically active metabolites of the Chinese traditional medicine, Dan Shen, prepared from the roots of Salvia miltiorrhiza Bunge.Methyltanshinquinone, the dihydro derivative of the natural product, methylenetanshinquinone, was similarly prepared.The effect of ultrasound in promoting the cycloadditions parallels that of high pressure and improved the regioselectivity in favour of the natural isomers.