127787-15-9

Basic information

• Product Name: N-(Bis-trimethylsilanyl-methyl)-3-methoxy-N-methyl-2-trimethylsilanyl-benzamide
• CAS NO: 127787-15-9
• Molecular Weight: 395.765
• Mol File: 127787-15-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(Bis-trimethylsilanyl-methyl)-3-methoxy-N-methyl-2-trimethylsilanyl-benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(Bis-trimethylsilanyl-methyl)-3-methoxy-N-methyl-2-trimethylsilanyl-benzamide(127787-15-9)
• EPA Substance Registry System: N-(Bis-trimethylsilanyl-methyl)-3-methoxy-N-methyl-2-trimethylsilanyl-benzamide(127787-15-9)

Safety Data

• Hazardous Substances Data: 127787-15-9(Hazardous Substances Data)

Upstream product

• 7290-99-5 N,N-dimethyl-m-methoxybenzamide 
• 75-77-4 chloro-trimethyl-silane 
• 127787-05-7 N-(Bis-trimethylsilanyl-methyl)-3-methoxy-N-methyl-benzamide 

Relevant articles and documents

α',α'-DISILYLATED TERTIARY BENZAMIDES AS DUAL ORTHO- AND α'-CARBANION SYNTHONS. AMIDE PETERSON OLEFINATION ROUTES TO N-BENZOYL ENAMINES, ISOQUINOLINES, AND DIBENZAZOCINES

α',α'-Disilylated benzamides 2, prepared by LiTMP/TMSCl in situ trap procedure, constitute ortho- and α'-carbanion synthons which provide N-benzoyl enamines (5), isoquinolines (6), dibenzoazocines (9) by Peterson olefination, and pyrroles (11) by cycloaddition.The conversion of 2 into other useful functionality is described.