127791-68-8

Basic information

• Product Name: 1,4-anhydro-5-O-(tert-butyldiphenylsilyl)-2-deoxy-3-O-(trimethylsilyl)-D-erythro-pent-1-enitol
• Synonyms: 1,4-anhydro-5-O-(tert-butyldiphenylsilyl)-2-deoxy-3-O-(trimethylsilyl)-D-erythro-pent-1-enitol
• CAS NO: 127791-68-8
• Molecular Weight: 426.703
• Mol File: 127791-68-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,4-anhydro-5-O-(tert-butyldiphenylsilyl)-2-deoxy-3-O-(trimethylsilyl)-D-erythro-pent-1-enitol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-anhydro-5-O-(tert-butyldiphenylsilyl)-2-deoxy-3-O-(trimethylsilyl)-D-erythro-pent-1-enitol(127791-68-8)
• EPA Substance Registry System: 1,4-anhydro-5-O-(tert-butyldiphenylsilyl)-2-deoxy-3-O-(trimethylsilyl)-D-erythro-pent-1-enitol(127791-68-8)

Safety Data

• Hazardous Substances Data: 127791-68-8(Hazardous Substances Data)

Upstream product

• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 101527-40-6 5'-O-tert-butyldiphenylsilylthymidine 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 50-89-5 thymidine 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 401813-15-8 (2S,3S)-2-(tert-butyldiphenylsilanyloxymethyl)tetrahydrofuran-3-ol 
• 91547-59-0 (2R,3S)-2-(hydroxymethyl)tetrahydrofuran-3-ol 
• 95049-01-7 5-O-(4,4'-dimethoxytriphenylmethyl)-1,4-anhydro-2-deoxy-D-ribitol 
• 4348-74-7 1-(α-D-arabinofuranosyl)-5-methyl-2,4(1H,3H)-pyrimidinedione 
• 127761-89-1 1-(2,3,5-tri-O-acetyl-α-D-arabinofuranosyl)thymine 
• 127761-86-8 1-(3'-(trimethylsilyl)-5'-(tert-butyldiphenylsilyl)-α-D-arabinofuranosyl)-5-methyl-2,4(1H,3H)-pyrimidinedione 
• 127761-83-5 1,4-anhydro-5-O-(tert-butyldiphenylsilyl)-2-deoxy-D-erythro-pent-1-enitol 
• 127761-84-6 (1R,3R,4R,5S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-trimethylsilanyloxy-2,6-dioxa-bicyclo[3.1.0]hexane 

Relevant articles and documents

Organocatalytic Conversion of Nucleosides to Furanoid Glycals

A class of organocatalysts that are highly active for the conversion of 2′-deoxynucleosides to furanoid glycals have been discovered. These phosphorimides, (Ph2PS)2NH and (Ph2PSe)2NH, were shown to effectively mediate persilylation of 2′-deoxynucleosides

One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation

A concise and highly efficient strategy for the synthesis of N-glycosyl imidazole analogues is reported. This reaction is based on a palladium catalysed decarboxylative allylation and three steps, namely, carbamation, decarboxylation and allylation are involved. All the substrates can afford the desired products with excellent yields and selectivities. the Partner Organisations 2014.