127839-79-6Relevant articles and documents
N-Benzyl-3-(tri-n-butylstannyl)thiopropionamide as Thiohomoenolatesynthon. Application to a Synthesis of Some Heterocycles
Takahata, Hiroki,Ohkura, Etsuko,Ikuro, Kazumi,Yamazaki, Takao
, p. 285 - 292 (2007/10/02)
N-Benzyl-3-(tri-n-butylstannyl)thiopropionamide undergoes metalexchange with n-butyllithium.The resulting thiohomoenolate dianion reacts with elestrophiles (aldehydes and ketones) to give the γ-hydroxythioamides, which are transformed into lactones, iminothiolactones, and thiolactams with simple elaboration.
