127901-15-9

Basic information

• Product Name: (Z)-2,2-Dimethyl-6-phenylsulfanyl-6-trimethylsilanyl-hex-5-en-3-ol
• CAS NO: 127901-15-9
• Molecular Weight: 308.56
• Mol File: 127901-15-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-2,2-Dimethyl-6-phenylsulfanyl-6-trimethylsilanyl-hex-5-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2,2-Dimethyl-6-phenylsulfanyl-6-trimethylsilanyl-hex-5-en-3-ol(127901-15-9)
• EPA Substance Registry System: (Z)-2,2-Dimethyl-6-phenylsulfanyl-6-trimethylsilanyl-hex-5-en-3-ol(127901-15-9)

Safety Data

• Hazardous Substances Data: 127901-15-9(Hazardous Substances Data)

Upstream product

• 6212-77-7 1-phenylthio-1-propyne 
• 123289-30-5 1-(Phenylthio)-1-(trimethylsilyl)-1,2-propadiene 
• 630-19-3 pivalaldehyde 
• 78905-13-2 phenyl 1-(trimethylsilyl)prop-2-en-1-yl sulfide 

Downstream Products

• 127901-13-7 3-(Methyldiphenylsilyl)-1-phenyl-4-phenylthio-4-trimethylsilyl-3-buten-1-ol 

Relevant articles and documents

Hydroalumination and related reactions of phenyl 1-(trimethylsilyl)propadienyl sulfide followed by quenching with carbonyl compounds

Phenyl 1-(trimethylsilyl)propadienyl sulfide undergoes a hydroalumination with diisobutylaluminum hydride (DIBAH) or lithium butyl(diisobutyl)aluminum hydride (BL-DIBAH). The adduct anion derived from DIBAH is regioselectively trapped with carbonyl compounds at the position α to the phenylthio moiety to give 1,3-dienes as Peterson olefination products; the anion derived from BL-DIBAH is trapped at the position γ to the phenylthio moiety to give 3-buten-1-ols. Silylmetalation and stanylalumination on the same acceptor have been also briefly investigated as equivalent reactions.