1279714-62-3

Basic information

• Product Name: (R,E)-5,5-dimethoxy-3-octyl-1-phenylsulfonylpent-1-ene
• Synonyms: (R,E)-5,5-dimethoxy-3-octyl-1-phenylsulfonylpent-1-ene
• CAS NO: 1279714-62-3
• Molecular Weight: 382.565
• Mol File: 1279714-62-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R,E)-5,5-dimethoxy-3-octyl-1-phenylsulfonylpent-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (R,E)-5,5-dimethoxy-3-octyl-1-phenylsulfonylpent-1-ene(1279714-62-3)
• EPA Substance Registry System: (R,E)-5,5-dimethoxy-3-octyl-1-phenylsulfonylpent-1-ene(1279714-62-3)

Safety Data

• Hazardous Substances Data: 1279714-62-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 53448-07-0 2-undecenal 
• 1279714-53-2 C₈H₉NO₄S 

Downstream Products

• 1279714-82-7 C₁₉H₂₈O₄S 
• 1279714-85-0 C₂₃H₃₇NO₄S 

Relevant articles and documents

Catalytic asymmetric synthesis of γ-substituted vinyl sulfones

A fast new entry for the stereoselective construction of γ-substituted vinyl sulfones is presented. The key for success is the use of a readily available chiral secondary amine catalyst that allows the use of base-sensitive β-nitroethyl sulfones as masked β-sulfonyl vinyl anions in conjugate additions. The method performed in a three-step one-pot operation gives access to a great variety of vinyl sulfones in good yields and with excellent enantioselectivities. The method has also been extended to other relatively base-sensitive β-electron-withdrawing-substituted nitroalkanes to afford products with manifold functionality, providing a quick entry to very attractive synthetic intermediates for organic synthesis.