128405-33-4

Basic information

• Product Name: trans--4-t-butyl-1-methoxycyclohexane
• CAS NO: 128405-33-4
• Molecular Weight: 171.284
• Mol File: 128405-33-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans--4-t-butyl-1-methoxycyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: trans--4-t-butyl-1-methoxycyclohexane(128405-33-4)
• EPA Substance Registry System: trans--4-t-butyl-1-methoxycyclohexane(128405-33-4)

Safety Data

• Hazardous Substances Data: 128405-33-4(Hazardous Substances Data)

Upstream product

• 4227-95-6 [13C]methyl iodide 
• 98-52-2 4-(1,1-dimethylethyl)-cyclohexanol 

Relevant articles and documents

Experimental studies of the anomeric effect. Part III. Rotameric preferences about the exo-cyclic c2-x bond in equatorial and axial 2-methoxy-and 2-methylamino-tetrahydropyrans

Values of3 J(CC), 3J(CH), 4J(CH) and 3J(HH), supported by n.O.enhancements, in nmr spectra of 2-methoxy- and 2-methyl-amino-tetrahydropyrans, point to a very strong preference for rotamers in which an exo-cyclic heteroatom lone pair is antiperiplanar to the endo-cyclic C2-O bond ("endo-anomeric effect").