128424-37-3Relevant articles and documents
A ferrocene based switchable molecular folding ruler
Scottwell, Syn?ve O.,Barnsley, Jonathan E.,McAdam, C. John,Gordon, Keith C.,Crowley, James D.
, p. 7628 - 7631 (2017)
A 2,2′-bipyridine-appended bis(ferrocene) three tiered molecular folding ruler, can be switched from a folded conformation to an extended conformation by the addition of [Cu(CH3CN)4](PF6) and 6,6′-dimesityl-2,2′-bipyridine
Ferrocene metallopolymers of intrinsic microporosity (MPIMs)
Ambrose, Kenson,Feldblyum, Jeremy I.,Nyayachavadi, Audithya,Rondeau-Gagné, Simon,Walter, Kelly G.,Zhai, Tianran
, p. 238 - 241 (2022/01/06)
We show here that non-network metallopolymers can possess intrinsic microporosity stemming from contortion introduced by metallocene building blocks. Metallopolymers constructed from ferrocenyl building blocks linked by phenyldiacetylene bridges are synth
Polytriazole bridged with 2,5-diphenyl-1,3,4-oxadiazole moieties: A highly sensitive and selective fluorescence chemosensor for Ag+
Cao, Shoupeng,Pei, Zhichao,Xu, Yongqian,Zhang, Ruina,Pei, Yuxin
, p. 45888 - 45896 (2015/06/08)
Fluorescent conjugated polytriazoles (FCP 1-4) containing both 2,5-diphenyl-1,3,5-oxadiazole (OXD) and 1,2,3-triazole moieties in the main chain were synthesized from aromatic diazide (1) and dialkynes (2-5) via click polymerization, respectively. In the polymers, OXDs (fluorophores) and triazole rings (generated via CuAAC acting as metal ion ligands) comprise a fluorescent system. The polytriazoles displayed relatively strong emission with quantum yields in the range of 0.20-0.28 at room temperature in DMF. The study on their ion-responsive properties showed that, although all four FCPs have good selectivity for Ag+, the integration of alkoxy side groups (methoxy for FCP 2, hexyloxy for FCP 3 and 2-ethylhexyloxy for FCP 4) to the main chains of the polytriazoles decreased their sensitivity for Ag+via alteration of the polymer aggregation status and electron density of the main chains. Thus FCP 1 is highly sensitive for Ag+, where its Ksv is as high as 1.44 × 105 M-1 and its lowest detection limit is in the ppb range (4.22 × 10-7 M). This study provides an efficient click approach to the synthesis of a novel fluorescence sensor for Ag+ detection, which could expand the application of click polymerization in designing fluorescence sensors based on the triazole unit. This journal is