128593-04-4Relevant articles and documents
Kinetics and Mechanism of Michael Addition of Pyrrolidine and Piperidine to a Polarized Double Bond
Kinastowski, Stefan,Kostecki, Marian
, p. 193 - 203 (2007/10/02)
The kinetics and mechanism of reaction of pyrrolidine and piperidine addition to trans-1-phenyl-2-(benzenesulphonyl)ethene (I) have been examined.The mechanism of addition of amines to compound I has been found to be analogous to that proposed for the reaction of trans-chalcone with amines.The addition of amine to the double bond of compound I takes place in a direct way.In the reaction of addition of amines to the polarized double bond three pathways can be distinguished: dimolecular one with participation of amide ions, dimolecular one with participation of free amine, and trimolecular one.