128622-75-3

Basic information

• Product Name: 1-<1-Hydroxy-4-t-butyl-cyclohexyl>-ethanesulfonic acid N,N-dimethylamide
• CAS NO: 128622-75-3
• Molecular Weight: 291.455
• Mol File: 128622-75-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-<1-Hydroxy-4-t-butyl-cyclohexyl>-ethanesulfonic acid N,N-dimethylamide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-<1-Hydroxy-4-t-butyl-cyclohexyl>-ethanesulfonic acid N,N-dimethylamide(128622-75-3)
• EPA Substance Registry System: 1-<1-Hydroxy-4-t-butyl-cyclohexyl>-ethanesulfonic acid N,N-dimethylamide(128622-75-3)

Safety Data

• Hazardous Substances Data: 128622-75-3(Hazardous Substances Data)

Upstream product

• 6338-68-7 Ethanesulfonic acid N,N-dimethylamide 
• 98-53-3 4-tercbutyl-cyclohexanone 

Relevant articles and documents

STEREOCHEMISTRY OF THE ADDITION OF α-METALLATED N,N-DIMETHYLSULFONAMIDES TO 4-t-BUTYLCYCLOHEXANONE

The effects of some reaction conditions on the aldol reaction of RCH(M)SO2N(CH3)2 and product stereochemistries are reported.Under thermodynamic control the reaction is nonstereoselective.Under kinetic control, stereoselectivity varies with R.For R = H, axial attack is slightly favoured, while equatorial attack is dominant for R = CH3.Dimethyl phenylmethanesulfonamide reacts highly stereoselectively.Equatorial attack is favoured with M = MgCl and M = Li, while M = Na gives 100percent axial attack.These, and several more observations cannot be interpreted in terms of current concepts of nucleophilic additions to 4-t-butylcyclohexanone.