128643-87-8

Basic information

• Product Name: ethyl 1-thio-6-O-(triphenylmethyl)-β-D-glucopyranoside
• Synonyms: ethyl 1-thio-6-O-(triphenylmethyl)-β-D-glucopyranoside
• CAS NO: 128643-87-8
• Molecular Weight: 466.598
• Mol File: 128643-87-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ethyl 1-thio-6-O-(triphenylmethyl)-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 1-thio-6-O-(triphenylmethyl)-β-D-glucopyranoside(128643-87-8)
• EPA Substance Registry System: ethyl 1-thio-6-O-(triphenylmethyl)-β-D-glucopyranoside(128643-87-8)

Safety Data

• Hazardous Substances Data: 128643-87-8(Hazardous Substances Data)

Upstream product

• 76-83-5 trityl chloride 
• 7473-36-1 ethyl 1-thio-β-D-glucopyranoside 
• 604-69-3 β-D-glucose pentaacetate 
• 32934-24-0 ethyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 
• 153439-99-7 ethyl 2,3,4-tri-O-benzoyl-6-O-trityl-1-thio-β-D-glucopyranoside 

Downstream Products

• 725228-65-9 ethyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranosiduronic acid 
• 162613-14-1 methyl (ethyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside)uronate 
• 153440-02-9 1-O-acetyl-2,3,4-tri-O-benzyl-6-O-(2,3,4-tri-O-benzyl-6-O-trityl-α-D-glucopyranosyl)-β-D-glucopyranose 
• 153440-01-8 1-O-acetyl-2,3,4-tri-O-benzyl-6-O-trityl-β-D-glucopyranose 
• 85011-35-4 1-O-acetyl-2,3,4-tri-O-benzyl-β-D-glucopyranose 
• 153439-99-7 ethyl 2,3,4-tri-O-benzoyl-6-O-trityl-1-thio-β-D-glucopyranoside 
• 144368-77-4 ethyl 2,3,4-tri-O-benzyl-1-thio-6-O-(triphenylmethyl)-β-D-glucopyranoside 
• 39483-51-7 ethyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside 

Relevant articles and documents

Synthesis of Glucuronoxylan Hexasaccharides by Preactivation-Based Glycosylations

The synthesis of two glucuronoxylans is described, which both consist of a pentaxylan backbone and a glucuronic acid linked to the 2 position in the fourth xylose residue from the reducing end. The two target molecules differ in the 4 position of the glucuronic acid where one is unsubstituted while the other contains a methyl ether. The pentaxylan backbone is assembled in four glycosylation reactions with phenyl thioglycoside donors. The couplings are performed by preactivation of the donor with in-situ-generated p-nitrobenzenesulfenyl triflate prior to addition of the acceptor. The glucuronic acids are then attached by Koenigs-Knorr glycosylations followed by deprotections. The syntheses employ a total of 8 steps from monosaccharide building blocks and afford the two glucuronoxylans in 12 and 15 % overall yield. The hexasaccharide products are valuable substrates for investigating the activity and specificity of glucuronoxylan-degrading enzymes.

SYNTHESIS OF THE TETRASACCHARIDE REPEATING-UNIT OF THE POLYSACCHARIDE FROM Klebsiella TYPE 23

Methyl 2-O-allyl-4-O-benzyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-L-rhamnopyranoside was obtained by condensing methyl 2-O-allyl-4-O-benzyl-α-L-rhamnopyranoside with tetra-O-acetyl-α-D-glucopyranosyl bromide.Benzylation, removal of the allyl g