128694-01-9Relevant articles and documents
A clean and efficient synthesis of 5-(2′-fluoro-2′,3′-dimethylbutan-3′-yl) substituted 1,2,4-oxadiazoles using silver tetrafluoroborate as a fluorodesulfurization reagent
Hemming, Karl,Morgan, Dexter T.,Smalley, Robert K.
, p. 83 - 86 (2000)
5-Ethylthio-6,6,7,7-tetramethyl substituted 4-oxa-1,3-diazabicyclo[3.2.0]hept-2-enes undergo fluorodesulfurization with silver tetrafluoroborate to furnish high yields of 5-(2′-fluoro-2′,3′-dimethylbutan-3′-yl) substituted 1,2,4-oxadiazoles. Ethylthio substituted 1,2,4-triaza- and 1,3-diaza-bicyclo[3.2.0]hept-2-enes behave in a similar fashion to yield 5-(2′-fluoro-2′,3′-dimethylbutan-3′-yl) substituted 1,2,4-triazoles and imidazoles, respectively.
1,3-Dipolar cycloadditions of 2-ethoxy- and 2-(ethylthio)-1-azetines with nitrilimines
Luheshi, Abdul-Basset N.,Smalley, Robert K.,Kennewell,Westwood
, p. 127 - 130 (2007/10/02)
1,3-Dipolar cycloadditions of diphenylnitrilimines with 2EtO-and 2EtS-tetramethyl-1-azetines (1a, b) are accompanied by ring-opening and loss of EtXH (X = O or S) to give 1,2,4-triazoles (3), whereas with N-(4-nitrophenyl) nitrilimines the expected cycloadducts and/or ring-opened products are formed.