128843-83-4

Basic information

• Product Name: Benzyl 2,3-anhydro-α-L-lyxopyranoside
• Synonyms: Benzyl 2,3-anhydro-α-L-lyxopyranoside
• CAS NO: 128843-83-4
• Molecular Weight: 222.241
• Mol File: 128843-83-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzyl 2,3-anhydro-α-L-lyxopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl 2,3-anhydro-α-L-lyxopyranoside(128843-83-4)
• EPA Substance Registry System: Benzyl 2,3-anhydro-α-L-lyxopyranoside(128843-83-4)

Safety Data

• Hazardous Substances Data: 128843-83-4(Hazardous Substances Data)

Upstream product

• 67412-71-9 (-)-benzyl 2,3-anhydro-β-D-ribopyranoside 
• 10065-72-2 L-Alanine methyl ester 
• 71204-45-0 benzyl 2,3-anhydro-4-triflyl-β-L-ribopyranoside 
• 2666-93-5 (S)-Leu-OMe 
• 10332-17-9 Met-OMe 
• 2768-50-5 dibenzyl L-glutamate 
• 2577-90-4 methyl (2S)-2-amino-3-phenylpropanoate 
• 24458-14-8 Lys(Z)-OBzl 

Downstream Products

• 104322-41-0 (+)-(2R)-benzyloxy-2,5-dihydrofuran-4-carboxaldehyde 
• 104322-42-1 (-)-(2S)-benzyloxy-2,5-dihydrofuran-4-carboxaldehyde 
• 104292-76-4 C₁₂H₁₁⁽²⁾HO₃ 

Relevant articles and documents

Chiral Aldehydes by Ring Contraction of Pento- and Hexopyranoside Epoxides

The chiral aldehydes (-)-(2S,5S)- and (-)-(2S,5R)-2-oxy>methyl>-5-methoxy-2,5-dihydrofuran-3-carbaldehyde (2 and 4) were synthesized in 60 and 15percent yield, respectively, by lithium bromide induced rearrangement of 6-O-silylated methyl 2,3- and 3,4-anhydro-α- and -β-D-hexopyranosides, obtained in two steps from methyl α- and β-D-glucopyranoside.Rearrangement of various other pento- and hexoside epoxides permitted the suggestion of probable reaction routes.Hydrogenation of the unsaturated aldehydes gave the corresponding saturated aldehydes in good yield.