128924-05-0

Basic information

• Product Name: 4'-(benzyloxy)-4-nitrobiphenyl
• CAS NO: 128924-05-0
• Molecular Weight: 305.333
• Mol File: 128924-05-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4'-(benzyloxy)-4-nitrobiphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-(benzyloxy)-4-nitrobiphenyl(128924-05-0)
• EPA Substance Registry System: 4'-(benzyloxy)-4-nitrobiphenyl(128924-05-0)

Safety Data

• Hazardous Substances Data: 128924-05-0(Hazardous Substances Data)

Upstream product

• 1528-74-1 4,4'-dinitrobiphenyl 
• 20194-18-7 sodium phenyl-methanolate 

Relevant articles and documents

Nucleophilic Substitution of Nitrite in Nitrobenzenes, Nitrobiphenyls and Nitronaphthalenes

Aromatic compounds, accessible only by multistep procedures, can be synthesized easily by nucleophilic substitution of nitrite in nitrobenzenes, nitrobiphenyls, and nitronaphthalines.Thus, meta-substituted phenols 3, 4, and 7 are obtained from 1,3-dinitrobenzene (1) and meta-substituted nitrobenzenes 6, as well as 3,5-disubstituted phenols 10 and 5-substituted resorcinol derivatives 11 from 3,5-disubstituted nitrobenzenes 9.The unsymmetrically substituted nitrobiphenyls 13, 15, 17, 19, 23, 24, and 26 are also available by nitrite exchange from the corresponding easily accessible dinitrobiphenyls 16, 18, 20, 22, and 25.A nitrite exchange with nucleophiles is easily possible in the 1,5-disubstituted naphthalenes 29, 34, while in the case of the 1,8-disubstituted naphthalenes 31, 36 only the chloro derivative 36 undergoes this exchange under much stronger conditions in low yield.