1289423-47-7

Basic information

• Product Name: (S)-(-)-2-hydroxy-3-nitro-2-(4-nitrophenyl)propanal
• CAS NO: 1289423-47-7
• Molecular Weight: 240.172
• Mol File: 1289423-47-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-(-)-2-hydroxy-3-nitro-2-(4-nitrophenyl)propanal(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(-)-2-hydroxy-3-nitro-2-(4-nitrophenyl)propanal(1289423-47-7)
• EPA Substance Registry System: (S)-(-)-2-hydroxy-3-nitro-2-(4-nitrophenyl)propanal(1289423-47-7)

Safety Data

• Hazardous Substances Data: 1289423-47-7(Hazardous Substances Data)

Upstream product

• 75-52-5 nitromethane 
• 4996-22-9 4-nitrophenylglyoxal 

Relevant articles and documents

The construction of quaternary stereocenters by the Henry reaction: Circumventing the usual reactivity of substituted glyoxals

The enantioselective Henry reaction between alkyl- and arylglyoxal hydrates and nitromethane catalyzed by CuII-iminopyridine complexes takes place regioselectively on the ketone carbonyl group to give chiral tertiary nitroaldols with high functional group density and enantiomeric excesses of up to 96 %. Both aromatic and aliphatic glyoxals are suitable substrates for this reaction.