1290083-26-9Relevant articles and documents
Iridium-promoted conversion of chlorosilanes to alkynyl derivatives in a one-pot reaction sequence
Kownacki, Ireneusz,Orwat, Bartosz,Marciniec, Bogdan
supporting information, p. 3051 - 3059 (2014/07/08)
By making use of the catalytic potential of the iridium system [{Ir(μ-Cl)(CO)2}2]/NEt(i-Pr)2 in the synthesis of silyl-functionalized alkynes via silylative coupling of terminal alkynes/diynes with iodosilanes, we propose
Silylative coupling of terminal alkynes with iodosilanes: New catalytic activation of sp-hybridized carbon-hydrogen bonds
Kownacki, Ireneusz,Marciniec, Bogdan,Dudziec, Beata,Kubicki, MacIej
experimental part, p. 2539 - 2545 (2011/06/27)
The [{Ir(μ-Cl)(CO)2}2] (I)-catalyzed reaction of terminal alkynes and diynes with Me3SiI with the aid of NEt(i-Pr)2 occurs smoothly, leading to the formation of mono- and bis-silyl-functionalized alkynyl derivat