1291105-05-9

Basic information

• Product Name: (R)-1-(2-chlorophenyl)ethane-1,2-diol-1,2-diacetate
• Synonyms: (R)-1-(2-chlorophenyl)ethane-1,2-diol-1,2-diacetate
• CAS NO: 1291105-05-9
• Molecular Weight: 256.686
• Mol File: 1291105-05-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-1-(2-chlorophenyl)ethane-1,2-diol-1,2-diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-(2-chlorophenyl)ethane-1,2-diol-1,2-diacetate(1291105-05-9)
• EPA Substance Registry System: (R)-1-(2-chlorophenyl)ethane-1,2-diol-1,2-diacetate(1291105-05-9)

Safety Data

• Hazardous Substances Data: 1291105-05-9(Hazardous Substances Data)

Upstream product

• 2039-87-4 2-chlorostyrene 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 32345-65-6 (DL)-o-chlorophenyl-1,2-ethanediol 
• 2754-27-0 trimethylsilyl acetate 
• 1255651-84-3 dimethyl-2,2'-((2-(diacetoxy-λ³-iodanyl)-1,3-phenylene)bis(oxy))(2R,2'R)-dipropionate 

Relevant articles and documents

Enantioselective Vicinal Diacetoxylation of Alkenes under Chiral Iodine(III) Catalysis

A procedure for the intermolecular enantioselective dioxygenation of alkenes under iodine(III) catalysis has been developed. This protocol employs Selectfluor as the terminal oxidant together with a defined C 2-symmetric aryl iodide as the organocatalyst. This enantioselective reaction proceeds under mild conditions and converts a series of terminal and internal styrenes into the corresponding vicinal diacetoxylation products with up to 96% ee.

Enantioselective Prevost and Woodward reactions using chiral hypervalent iodine(iii): Switchover of stereochemical course of an optically active 1,3-dioxolan-2-yl cation

Optically active 1,3-dioxolan-2-yl cation intermediates were generated during enantioselective dioxyacetylation of alkene with chiral hypervalent iodine(III). Regioselective attack of a nucleophile toward the intermediate resulted in reversal of enantioselectivity of the dioxyacetylation. The Royal Society of Chemistry.