129217-11-4

Basic information

• Product Name: 3-benzoylhexahydrobenzoxazol-2(3H)-one
• Synonyms: 3-benzoylhexahydrobenzoxazol-2(3H)-one
• CAS NO: 129217-11-4
• Molecular Weight: 245.278
• Mol File: 129217-11-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-benzoylhexahydrobenzoxazol-2(3H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-benzoylhexahydrobenzoxazol-2(3H)-one(129217-11-4)
• EPA Substance Registry System: 3-benzoylhexahydrobenzoxazol-2(3H)-one(129217-11-4)

Safety Data

• Hazardous Substances Data: 129217-11-4(Hazardous Substances Data)

Upstream product

• 4461-33-0 benzoyl isocyanate 
• 110-83-8 cyclohexene 
• 286-20-4 cyclohexane-1,2-epoxide 
• 5610-59-3 fulminic acid ; silver-salt 
• 98-88-4 benzoyl chloride 
• 129217-10-3 trans-2-bromocyclohexyl benzoylcarbamate 
• 56-23-5 tetrachloromethane 
• 101937-68-2 (+/-)-cis-1-benzoylamino-2-chlorocarbonyloxy-cyclohexane 

Relevant articles and documents

A facile one-pot solid-phase synthesis of oxazolidin-2-ones using polymer-supported 2-hydroxyalkyl selenide reagent

A simple, efficient and environmentally friendly procedure for one-pot solid-phase synthesis of 2-oxazolidinones in moderate to good yields by reaction of polystyrene-supported 2-hydroxyalkyl selenide with benzoyl isocyanate and subsequent oxidation/cycli

Formation of N-Tributylstannyl Heterocycle from Bis(tributyltin) Oxide and ω-Haloalkyl Isocyanate. One-Pot Convenient Synthesis of 2-Oxazolidinones and Tetrahydro-2H-1,3-oxazin-2-one

Novel types of compounds, N-tributylstannyl-2-oxazolidinone (4a) and tetrahydro-2H-1,3-oxazin-2-one (4b), are formed from the adduct of (n-Bu3Sn)2O (1) with ω-haloalkyl isocyanate (2), and the subsequent coupling reaction with alkyl halides gives a variety of N-substituted 2-oxazolidinones and tetrahydro-2-oxazinones in a one-pot procedure.Both the cyclization and the coupling reaction proceed quantitatively in the presence of HMPA which enhances the reactivity of the Sn-heteroatom bond by coordination.