1292281-35-6Relevant articles and documents
Functionalization of acetalic C(sp3)-H bonds by scandium(III) triflate-catalyzed intramolecular redox reactions: Tandem 1,4-hydride transfer/1,5-cyclization processes leading to protected 1-indanones
Alajarin, Mateo,Marin-Luna, Marta,Vidala, Angel
, p. 557 - 562 (2011/04/26)
A new C-C bond forming reaction leading to adjacent quaternary carbons is reported. It is a one-pot hydride shift/cyclization process facilitated by the hydricity of the acetalic C-H bonds, with benzylidenemalonate fragments as electrophilic hydride accep