129353-28-2

Basic information

• Product Name: 8-Methylene-1-phenylbicyclo<5.1.0>octane
• CAS NO: 129353-28-2
• Molecular Weight: 198.308
• Mol File: 129353-28-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 8-Methylene-1-phenylbicyclo<5.1.0>octane(CAS DataBase Reference)
• NIST Chemistry Reference: 8-Methylene-1-phenylbicyclo<5.1.0>octane(129353-28-2)
• EPA Substance Registry System: 8-Methylene-1-phenylbicyclo<5.1.0>octane(129353-28-2)

Safety Data

• Hazardous Substances Data: 129353-28-2(Hazardous Substances Data)

Upstream product

• 31304-51-5 1-chloro-1-methylcarbene 
• 25308-75-2 1-Phenylcycloheptene 

Relevant articles and documents

Chloropalladation of 1-aryl-ω-methylenebicyclo[n.1.0]alkanes

The chloropalladation of 1-aryl-ω-methylenebicyclo[n.1.0]alkanes affords a mixture of (1-aryl-3-chloro-2-methylenecycloalkyl) - and (3-aryl-3-chloro-2-methylenecycloalkyl)palladium chloride dimers in excellent yield. These products have been characterized by 1H NMR spectroscopy. The regioselectivity of the chloropalladation appears to be dependent on ring strain, steric hinderance and to some extent, the ability of the aryl substituent to stabilize partial positive charge.