129379-65-3Relevant articles and documents
The inverted micellar catalysis of the reaction of 2-aminomethylphenols with 4-nitrophenyl bis(chloromethyl)phosphinate
Zhil'tsova, E. P.,Kudryavtseva, L. A.,Shagidullina, R. A.
, p. 274 - 277 (1999)
The parameters of the reaction of para-substituted 2-aminomethylphenols with 4-nitrophenyl bis(chloromethyl)phosphinate in toluene catalyzed by reversed micelles of polyethylene glycol-600 monolaurate depend on the nucleophile structure. The efficiency of
Effect of sodium dodecyl sulfate on the reactivity of 2-dimethylaminomethyphenol with 4-nitrophenylbis(chloromethyl)phosphinate
Ryzhkina, I. S.,Kudryavtseva, L. A.,Usol'tseva, N. V.
, p. 1879 - 1882 (2007/10/03)
The reactivity of 2-dimethylaminomethylphenol (1) toward 4-nitrophenylbis(chloromethyl)phosphinate (2) was studied in micellar solutions and lyotropic liquid-crystalline mesophase of the sodium dodecyl sulfate (SDS)-water system.The reaction between 1 and 2 is inhibited in the presence of SDS, which is explained by the shift of the acid-base equilibrium of 1 toward the formation of a nonreactive protonated form. - Keywords: micelles, liquid crystals, rate constant, sodium dodecyl sulfate, 2-dimethylaminomethylphenol, 4-nitrophenylbis(chloromethyl)phosphinate