129413-28-1

Basic information

• Product Name: (1S,2R,5R,6R,7S,8R,12S,13S,17R)-15-(4-Bromo-phenyl)-7-hydroxy-2,5,6,8,12,17-hexamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione
• CAS NO: 129413-28-1
• Molecular Weight: 525.48
• Mol File: 129413-28-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2R,5R,6R,7S,8R,12S,13S,17R)-15-(4-Bromo-phenyl)-7-hydroxy-2,5,6,8,12,17-hexamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,5R,6R,7S,8R,12S,13S,17R)-15-(4-Bromo-phenyl)-7-hydroxy-2,5,6,8,12,17-hexamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione(129413-28-1)
• EPA Substance Registry System: (1S,2R,5R,6R,7S,8R,12S,13S,17R)-15-(4-Bromo-phenyl)-7-hydroxy-2,5,6,8,12,17-hexamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione(129413-28-1)

Safety Data

• Hazardous Substances Data: 129413-28-1(Hazardous Substances Data)

Upstream product

• 24856-58-4 1,1-dimethoxy-1-(4-bromophenyl)methane 
• 129413-27-0 (2R,3S,4R,5R,6R)-3,5-Bis-benzyloxy-2,4,6-trimethyl-7-oxo-heptanoic acid (1R,2S,3S,4R)-3-benzyloxy-6-(dimethoxy-phosphoryl)-1,2,4-trimethyl-5-oxo-hexyl ester 

Downstream Products

• 119870-70-1 C₂₇H₃₇BrO₇ 
• 119887-69-3 (1S,2R,5R,6R,7R,8R,9R,12S,13S,17R)-15-(4-Bromo-phenyl)-7,9-dihydroxy-2,5,6,8,12,17-hexamethyl-10-methylene-4,14,16-trioxa-bicyclo[11.3.1]heptadecan-3-one 
• 119870-69-8 C₂₇H₃₉BrO₇ 
• 129413-29-2 (1S,2R,5R,6R,7S,8R,12S,13S,17R)-15-(4-Bromo-phenyl)-7-hydroxy-2,5,6,8,12,17-hexamethyl-10-methylene-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione 

Relevant articles and documents

The total synthesis of oleandomycin

The key aglycone, oleandolide, has been synthesized by coupling two segments of C1-C7 and C8-C14 portions, which are enantiospecifically derived from methyl α-L- and D-rhamnosides, respectively.