129432-79-7

Basic information

• Product Name: 6-phenyl-hex-2-ene-1-ol
• Synonyms: 6-phenyl-hex-2-ene-1-ol
• CAS NO: 129432-79-7
• Molecular Weight: 176.258
• Mol File: 129432-79-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 6-phenyl-hex-2-ene-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 6-phenyl-hex-2-ene-1-ol(129432-79-7)
• EPA Substance Registry System: 6-phenyl-hex-2-ene-1-ol(129432-79-7)

Safety Data

• Hazardous Substances Data: 129432-79-7(Hazardous Substances Data)

Upstream product

• 14370-82-2 allyl phenyl selenide 
• 637-59-2 1-Bromo-3-phenylpropane 
• 1823-14-9 5-phenyl-1-pentyne 
• 77877-57-7 6-phenyl-2-hexyn-1-ol 
• 3277-89-2 phenethylmagnesium bromide 
• 7523-44-6 4-Chloro-2-buten-1-ol 

Downstream Products

• 144465-39-4 1-Acetyl-2-(4-phenyl-butyl)-cyclopropanecarboxylic acid methyl ester 
• 129432-83-3 (E)-(6-bromohex-4-en-1-yl)benzene 

Relevant articles and documents

Acid-catalyzed chirality-transferring intramolecular Friedel-Crafts cyclization of α-hydroxy-α-alkenylsilanes

Acid-catalyzed intramolecular Friedel-Crafts cyclization of optically active α-hydroxy-α-alkenylsilanes possessing a benzene ring (>99% ee) with TMSOTf as a Lewis acid gave enantio-enriched tetrahydronaphthalenes (up to 98% ee). The silyl group attached to the chiral carbon played a crucial role in the chirality transfer.

Synthesis of 1-Acyl-2-alkylcyclopropanecarboxylic Esters from 2-Alkenylphosphonium Salts

The one-pot reaction of allyltriphenylphosphonium bromide with the sodium salts of β-keto esters leads to the formation of alkyl 1-acyl-2-alkylcyclopropanecarboxylates.