129585-06-4Relevant articles and documents
Preparation of 2-oxygen derivatives of 1,2-oxaborolane from 2-allyloxy-1,2-oxaborolane
Weike, Zhou,Weiming, Lo,Gaoyi, Zhang,Hongxun, Ding,Shaofang, Liang
, p. 131 - 146 (2007/10/02)
2-Allyloxy-1,2-oxaborolane (V), readily obtained by hydroboration of allyl alcohol with borane reagents such as KBH4-HOAc, was used as a key reactant in the synthesis of a series of 2-oxygen derivatives of 1,2-oxaborolane. 2-Allyl-1,2-oxaborolane (XXIII) and 2-hydro-1,2-oxaborolane dimethylsulfide complex (XXIV), prepared from the reaction of V with allylmagnesium bromide and dimethylsulfideborane complex (BMS) respectively, were also used as the reactive intermediates for some of the lower 2-alkyloxy-1,2-oxaborolanes.Five procedures and other probable routes from V to 2-oxygen derivatives of 1,2-oxaborolane are described.