1296206-73-9

Basic information

• Product Name: (R)-1-(tert-butyldimethylsilyl)prop-2-en-1-ol
• Synonyms: (R)-1-(tert-butyldimethylsilyl)prop-2-en-1-ol
• CAS NO: 1296206-73-9
• Molecular Weight: 172.343
• Mol File: 1296206-73-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-1-(tert-butyldimethylsilyl)prop-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-(tert-butyldimethylsilyl)prop-2-en-1-ol(1296206-73-9)
• EPA Substance Registry System: (R)-1-(tert-butyldimethylsilyl)prop-2-en-1-ol(1296206-73-9)

Safety Data

• Hazardous Substances Data: 1296206-73-9(Hazardous Substances Data)

Upstream product

• 1266551-35-2 (S)-1-(tert-butyldimethylsilyl)prop-2-en-1-ol 
• 62-23-7 4-nitro-benzoic acid 

Relevant articles and documents

Stereoselective anti-SN2′ Mitsunobu reaction of α-hydroxy-α-alkenylsilanes

A novel silyl group-directed anti-SN2′ reaction of allylic alcohols under Mitsunobu reaction conditions is described. The Mitsunobu reaction of α-hydroxy-α-alkenylsilanes with a TBS or TIPS group gave the anti-SN2′ product, in which regio- and stereochemical outcomes of the reaction depended on the steric bulkiness of the silyl group.