129679-91-0

Basic information

• Product Name: (meso-tetra-p-tolylporphyrinato)titanium(IV) dichloride
• Synonyms: (meso-tetra-p-tolylporphyrinato)titanium(IV) dichloride
• CAS NO: 129679-91-0
• Molecular Weight: 787.627
• Mol File: 129679-91-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (meso-tetra-p-tolylporphyrinato)titanium(IV) dichloride(CAS DataBase Reference)
• NIST Chemistry Reference: (meso-tetra-p-tolylporphyrinato)titanium(IV) dichloride(129679-91-0)
• EPA Substance Registry System: (meso-tetra-p-tolylporphyrinato)titanium(IV) dichloride(129679-91-0)

Safety Data

• Hazardous Substances Data: 129679-91-0(Hazardous Substances Data)

Upstream product

• 31011-57-1 tetrachlorobis(tetrahydrofuran)titanium(IV) 

Downstream Products

• 263151-95-7 (meso-tetra-p-tolylporphyrinato)Ti=NNMe₂ 
• 65496-72-2 oxotitanium(IV) meso-tetrakis(4-methylphenyl)porphinato 
• 185549-02-4 (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(OMe)2 
• 185549-05-7 (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(OPh)Cl 
• 185549-06-8 (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(OCH₃)Cl 
• 185549-01-3 (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(OPh)2 
• 148509-02-8 (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(η2-3-hexyne) 
• 199998-29-3 trans-(meso-tetra-p-tolylporphyrinato)Ti(t-BuNC)2 
• 150392-79-3 trans-bis(4-picoline)(tetratolylporphyrinato)titanium(II) 
• 150392-80-6 (meso-5,10,15,20-tetra-p-tolylporphyrinato)bis(pyridine)Ti 
• 185549-07-9 (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(NPh₂)Cl 
• 185549-03-5 (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(O-t-Bu)2 
• 185549-12-6 (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(O(t)Bu)Cl 
• 199998-28-2 trans-(meso-tetra-p-tolylporphyrinato)Ti(THF)2 

Relevant articles and documents

Synthesis of early transition metal porphyrin halide complexes: First structural characterization of a vanadium(III) porphyrin complex

A general method for the preparation of early transition metal porphyrin halide complexes using a porphyrin dianion, (THF)2Li2(POR) (POR = OEP, TTP; OEP = octaethylporphyrinato, TTP = meso-tetra-p-tolylporphyrinato), and the appropriate metal halide complex, MXn (MXn = VCl3(THF)3, TiCl4(THF)2, TiCl3(THF)3, MoCl4(CH3CN)2, WCl4), is described. The structure of (TTP)VIIICl·THF (2·THF) has been determined by single-crystal X-ray diffraction analysis. Complex 2·THF crystallizes in the centrosymmetric space group P21/m with a = 11.968(2) A?, b = 17.072(3) A?, c = 12.649(2) A?, β = 98.62(2)°, V = 2555.2(8) A?3, Z = 2, R = 4.6%, and Rw = 6.7%. The V-Cl bond length is 2.272(1) A?, the V-N bond lengths range from 2.040(4) to 2.050(3) A?, and the V-O bond distance is 2.141 (3) A?.