129801-09-8

Basic information

• Product Name: 1-Cyclohexyl-1-(1,2-epoxycyclohexyl)ethylene
• CAS NO: 129801-09-8
• Molecular Weight: 206.328
• Mol File: 129801-09-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexyl-1-(1,2-epoxycyclohexyl)ethylene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexyl-1-(1,2-epoxycyclohexyl)ethylene(129801-09-8)
• EPA Substance Registry System: 1-Cyclohexyl-1-(1,2-epoxycyclohexyl)ethylene(129801-09-8)

Safety Data

• Hazardous Substances Data: 129801-09-8(Hazardous Substances Data)

Upstream product

• 102104-37-0 1-(Benzenesulfinyl-chloro-cyclohexyl-methyl)-cyclohexanol 
• 74598-74-6 cyclohex-1-en-1-yl(cyclohexyl)methanone 
• 95110-49-9 2'-cyclohexyl-2'-phenylsulfinylspiro 
• 19493-09-5 Methylenetriphenylphosphorane 
• 108-94-1 cyclohexanone 
• 104354-60-1 cyclohexylchloromethyl phenyl sulfoxide 

Relevant articles and documents

A Novel Synthesis of Methylenecyclopropane Spiro-Linked with Cycloalkanes via a Cyclization of Allylic Epoxides and Its Application to a Synthesis of Fused 3-Methylfurans

Ring closure of allylic epoxides derived from 1-chloroalkyl phenyl sulfoxides and cyclic ketones with lithium diisopropylamide (LDA) in 3-Exo-Tet mode gave spiro-linked methylenecyclopropanes having a hydroxyl group in good yields.Oxidation of these compounds gave ketones, which were then treated with p-toluenesulfonic acid in 1,4-dioxane or DMSO at 100 deg C to give fused 3-methylfurans in good overall yields.This procedure was applied to a synthesis of menthofuran from 4-methylcyclohexanone.