129846-67-9

Basic information

• Product Name: 4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene
• Synonyms: 4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene
• CAS NO: 129846-67-9
• Molecular Weight: 260.102
• Mol File: 129846-67-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene(129846-67-9)
• EPA Substance Registry System: 4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene(129846-67-9)

Safety Data

• Hazardous Substances Data: 129846-67-9(Hazardous Substances Data)

Upstream product

• 1514-87-0 metyhyl chlorodifluoroacetate 
• 106-95-6 allyl bromide 
• 102061-82-5 sodium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfinate 
• 556-56-9 allyl iodid 
• 423-39-2 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane 

Relevant articles and documents

Synthese de 3-perfluoroalkylprop-1-enes RF-CH2-CH=CH2

The reactions of perfluoroalkyl iodides with allylbromide or chloride, in the presence of solid potassium hydroxide KOH give 3-perfluoroalkylprop-1-enes RFCH2CH=CH2 in good yields under mild conditions. This reaction represents a synthetically viable and convenient route to such compounds.

Reaction of Perfluoroalkanesulfinates with Allyl and Propargyl Halides. A Convenient Synthesis of 3-(Perfluoroalkyl)prop-1-enes and 3-(Perfluoroalkyl)allenes

The reaction of perfluoroalkanesulfinates, RfCF2SO2Na, with allyl and propargyl halides, in the presence of (NH4)2S2O8, gave 3-(perfluoroalkyl)prop-1-enes (RfCH2CH=CH2) and 3-(perfluoroalkyl)allenes (RfCH=C=CH2), respectively, in good yield.Evidence is presented for a radical addition-elimination mechanism for the reaction.The reaction represents a synthetically viable and convenient route to such compounds.