129889-18-5

Basic information

• Product Name: 2,3,4,6-Tetra-O-benzyl-β-D-glucopyranosyl trifluoroacetate
• CAS NO: 129889-18-5
• Molecular Weight: 636.665
• Mol File: 129889-18-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-Tetra-O-benzyl-β-D-glucopyranosyl trifluoroacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-Tetra-O-benzyl-β-D-glucopyranosyl trifluoroacetate(129889-18-5)
• EPA Substance Registry System: 2,3,4,6-Tetra-O-benzyl-β-D-glucopyranosyl trifluoroacetate(129889-18-5)

Safety Data

• Hazardous Substances Data: 129889-18-5(Hazardous Substances Data)

Upstream product

• 38768-81-9 2,3,4,6-Tetra-O-benzyl-α-D-glucose 
• 407-25-0 trifluoroacetic anhydride 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 

Downstream Products

• 132817-37-9 1,2,3-Trimethoxy-4-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)benzene 
• 132817-45-9 2,3,4-Trimethoxy-1-phenylsulfinyl-5-(2,3,4,6-tetra-O-methoxycarbonyl-β-D-glucopyranosyl)benzene 
• 132817-44-8 2,3,4-Trimethoxy-1-phenylthio-5-(2,3,4,6-tetra-O-methoxycarbonyl-β-D-glucopyranosyl)benzene 
• 132817-41-5 1,2,3-Trimethoxy-4-methoxycarbonyl-6-(2,3,4,6-tetra-O-methoxycarbonyl-β-D-glucopyranosyl)benzene 
• 132817-40-4 1-Bromo-2,3,4-trimethoxy-5-(2,3,4,6-tetra-O-methoxycarbonyl-β-D-glucopyranosyl)benzene 
• 132817-39-1 1,2,3-Trimethoxy-4-(2,3,4,6-tetra-O-methoxycarbonyl-β-D-glucopyranosyl)benzene 
• 132817-43-7 1,2,3-Trimethoxy-4-methoxycarbonyl-6-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene 
• 132817-42-6 2,3,4-Trimethoxy-5-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yl)-benzoic acid methyl ester 
• 132817-38-0 (2R,3S,4R,5R,6S)-2-Hydroxymethyl-6-(2,3,4-trimethoxy-phenyl)-tetrahydro-pyran-3,4,5-triol 
• 124917-60-8 tetra-O-benzyl-1-<(2'-hydroxy)ethyl>-glucopyranose 
• 81972-20-5 2-(2',3',4',6'-tetra-O-benzyl-β-D-glucopyranosyl)ethanol 
• 124813-83-8 1-(5-α-cholestan-3β-yl)-2-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)ethanone 
• 137410-38-9 3,5,8-Trimethoxy-1-methyl-9,10-dioxo-7-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-9,10-dihydro-anthracene-2-carboxylic acid ethyl ester 
• 137410-35-6 ethyl 7-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-3,5,8,9,10-pentamethoxy-1-methylanthracene-2-carboxylate 

Relevant articles and documents

Synthesis of bergenin-type C-glucosylarenes

Reaction of 1,2,3-trimethoxybenzene with 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl trifluoroacetate (5) in the presence of BF3*OEt2 afforded the 4-β-C-glycosylarene 6.Hydrogenolysis of 6, then O-methoxycarbonylation, and bromination gave 1-bromo-2,3,4-tri

The First Direct Method for C-Glucopyranosyl Derivatization of 2,3,4,6-Tetra-O-benzyl-D-glucopyranose

Commercially available 2,3,4,6-tetra-O-benzyl-D-glucopyranose, activated by trifluoroacetic anhydride reacts, in the presence of Lewis acids, with various silyl enol ethers or with allylsilane to yield C-D-glucopyranosyl derivatives of the α-configuration