1301717-34-9

Basic information

• Product Name: (3S,4S)-3-(4’,4’,5’,5’-tetramethyl-1’,3’,2’-dioxaborolanyl)-4-methyl-4-phenylhex-1-ene
• Synonyms: (3S,4S)-3-(4’,4’,5’,5’-tetramethyl-1’,3’,2’-dioxaborolanyl)-4-methyl-4-phenylhex-1-ene
• CAS NO: 1301717-34-9
• Molecular Weight: 300.249
• Mol File: 1301717-34-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4S)-3-(4’,4’,5’,5’-tetramethyl-1’,3’,2’-dioxaborolanyl)-4-methyl-4-phenylhex-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S)-3-(4’,4’,5’,5’-tetramethyl-1’,3’,2’-dioxaborolanyl)-4-methyl-4-phenylhex-1-ene(1301717-34-9)
• EPA Substance Registry System: (3S,4S)-3-(4’,4’,5’,5’-tetramethyl-1’,3’,2’-dioxaborolanyl)-4-methyl-4-phenylhex-1-ene(1301717-34-9)

Safety Data

• Hazardous Substances Data: 1301717-34-9(Hazardous Substances Data)

Upstream product

• 1201898-74-9 (S)-4,4,5,5-tetramethyl-2-(2-phenylbutan-2-yl)-1,3,2-dioxaborolane 
• 107-05-1 3-chloroprop-1-ene 

Downstream Products

• 1301717-45-2 (3S,4R)-4-methyl-4-phenylhex-1-en-3-ol 
• 1428538-04-8 (1S,3E,5S)-5-methyl-1-(4-nitrophenyl)-5-phenylhept-3-en-1-ol 
• 1428537-90-9 (1S,3E,5S)-5-methyl-1,5-diphenylhept-3-en-1-ol 
• 1428537-92-1 (1R,3Z,5S)-5-methyl-1,5-diphenylhept-3-en-1-ol 

Relevant articles and documents

Enantioselective construction of quaternary stereogenic centers from tertiary boronic esters: Methodology and applications

Pin it down: A range of substrates that bear versatile functional groups with quaternary stereogenic centers have been prepared with very high enantioselectivity from tertiary boronic esters (see scheme; Cb=N,N-diisopropylcarbamoyl, pin=pinacolato). The preparation of allylboronic esters bearing contiguous quaternary and tertiary stereogenic centers, and applications to natural product synthesis are also reported.