130240-26-5Relevant articles and documents
Chemo- and enantioselective hydrogenation of the activated keto group of fluorinated β-diketones
Hess, Reto,Diezi, Simon,Mallat, Tamas,Baiker, Alfons
, p. 251 - 257 (2004)
Asymmetric hydrogenation of the activated carbonyl group of 1,1,1-trifluoro-2,4-diketones was studied over Pt/Al2O3 modified by various chiral 1,2-aminoalcohols and amines. The best chiral modifiers were cinchonidine and O-methyl-cin
Cyclodehydration of fluorinated diols using the mitsunobu reaction: Highly efficient synthesis of trifluoromethylated cyclic ethers
Prakash, G. K. Surya,Do, Clement,Wang, Fang,Mathew, Thomas,Olah, George A.
experimental part, p. 1891 - 1898 (2010/08/20)
Synthesis of trifluoromethylated cyclic ethers has been achieved via the Mitsunobu cyclodehydration of fluorinated diols with high efficacy. The methodology is found to be widely applicable to the synthesis of cyclic ethers with varying ring size (3-7) fr