130256-51-8

Basic information

• Product Name: (2S,3S,4S)-2-Benzyloxy-4,5-dimethyl-hex-5-en-3-ol
• Synonyms: (2S,3S,4S)-2-Benzyloxy-4,5-dimethyl-hex-5-en-3-ol
• CAS NO: 130256-51-8
• Molecular Weight: 234.338
• Mol File: 130256-51-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3S,4S)-2-Benzyloxy-4,5-dimethyl-hex-5-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,4S)-2-Benzyloxy-4,5-dimethyl-hex-5-en-3-ol(130256-51-8)
• EPA Substance Registry System: (2S,3S,4S)-2-Benzyloxy-4,5-dimethyl-hex-5-en-3-ol(130256-51-8)

Safety Data

• Hazardous Substances Data: 130256-51-8(Hazardous Substances Data)

Upstream product

• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 78-79-5 isoprene 
• 513-35-9 2-methyl-but-2-ene 

Relevant articles and documents

Addition of a tiglyltitanocene to chiral aldehydes: factors influencing simple and diastereofacial stereoselectivities

The η3-tiglyltitanium(III) complex formed in situ from isoprene was reacted with a series of chiral aldehydes, some of which bear α- and/or β-benzyloxy groups, or a remote double bond. anti Diastereomeric homoallylic alcohols were formed stereospecifically starting from the alkoxy-free saturated aldehydes.In contrast, mixtures of anti and syn stereomers were obtained by using alkoxy- or ε-unsaturated aldehydes.The simple diastereoselectivities and diastereofacial selectivities observed are rationalized in terms of the chelation versus non-chelation-controlled process. - Keywords: η3-tiglyltitanocene complex; chiral aldehyde; stereoselectivity; chelation control