130259-46-0

Basic information

• Product Name: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-methoxycarbonylamino-β-D-glucopyranoside
• Synonyms: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-methoxycarbonylamino-β-D-glucopyranoside
• CAS NO: 130259-46-0
• Molecular Weight: 445.467
• Mol File: 130259-46-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-methoxycarbonylamino-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-methoxycarbonylamino-β-D-glucopyranoside(130259-46-0)
• EPA Substance Registry System: cyclohexyl 3,4,6-tri-O-acetyl-2-deoxy-2-methoxycarbonylamino-β-D-glucopyranoside(130259-46-0)

Safety Data

• Hazardous Substances Data: 130259-46-0(Hazardous Substances Data)

Upstream product

• 5432-46-2 1,3,4,6-tetra-O-acetyl-D-glucosamine hydrochloride 
• 61566-44-7 (2S,3R,4R,5S,6R)-6-(acetoxymethyl)-3-(methoxycarbonylamino)tetrahydro-2H-pyran-2,4,5-triyl triacetate 
• 7597-81-1 (2S,3R,4R,5S,6R)-6-(acetoxymethyl)-3-((E)-(4-methoxybenzylidene)amino)tetrahydro-2Hpyran-2,4,5-triyl triacetate 
• 130259-36-8 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-6-bromo-5-methoxycarbonylamino-tetrahydro-pyran-4-yl ester 
• 108-93-0 cyclohexanol 

Relevant articles and documents

The use of N-alkoxycarbonyl derivatives of 2-amino-2-deoxy-D-glucose as donors in glycosylation reactions

1,3,4,6-Tetra-O-acetyl-2-alkoxycarbonylamino-2-deoxy-β-D-glucopyranoses and 3,4,6-tri-O-acetyl-2-alkoxycarbonylamino-2-deoxy-α-D-glucopyranosyl bromides have been used as donors in glycosylation reactions with model alcohols. β-Glycosides were obtained in good yields and with a high degree of 1,2-trans stereoselectivity.An oxazolidone was formed as the main product from the reaction of some of the glucopyranosylbromides with alcohols of low reactivity, but the formation of all products could be interpreted by a strong participation of the alkoxycarbonylamino group.