130281-37-7

Basic information

• Product Name: (Z)-1-hexyldimethylsilyl-1,2-bis(trimethylsilyl)ethane
• Synonyms: (Z)-1-hexyldimethylsilyl-1,2-bis(trimethylsilyl)ethane
• CAS NO: 130281-37-7
• Molecular Weight: 314.734
• Mol File: 130281-37-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-1-hexyldimethylsilyl-1,2-bis(trimethylsilyl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-hexyldimethylsilyl-1,2-bis(trimethylsilyl)ethane(130281-37-7)
• EPA Substance Registry System: (Z)-1-hexyldimethylsilyl-1,2-bis(trimethylsilyl)ethane(130281-37-7)

Safety Data

• Hazardous Substances Data: 130281-37-7(Hazardous Substances Data)

Upstream product

• 63246-85-5 hexyldimethylsilane 
• 14630-40-1 Bis(trimethylsilyl)ethyne 
• 130281-22-0 (E)-1-hexyldimethylsilyl-1,2-bis(trimethylsilyl)ethane 

Relevant articles and documents

Platinum-catalyzed elimination-addition reactions of trisilylethenes

(E)-1-Hexyldimethylsilyl-1,2-bis(trimethylsilyl)ethene (1) and (E)-1-(3'-butyl-1',3'-tetramethyldisiloxanyl)-1,2-bis(trimethylsilyl)ethene (7) undergo isomerization-redistribution reactions catalyzed by platinum.Each of them is converted into its (Z)-isomer and ethenes bearing one trimethylsilyl group and two substituted silyl groups as major products.The proposed mechanism for the reactions involves a sequence of eliminations of hydrosilanes from the ethenes and re-addition to them.Oxygen greatly affects the reaction apparently accelerating anti-elimination of hydrosilanes.