130293-09-3

Basic information

• Product Name: Acetic acid, [(phenylmethyl)amino]thioxo-, 1,1-dimethylethyl ester
• CAS NO: 130293-09-3
• Molecular Formula: C13H17NO2S
• Molecular Weight: 251.349
• Mol File: 130293-09-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid, [(phenylmethyl)amino]thioxo-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [(phenylmethyl)amino]thioxo-, 1,1-dimethylethyl ester(130293-09-3)
• EPA Substance Registry System: Acetic acid, [(phenylmethyl)amino]thioxo-, 1,1-dimethylethyl ester(130293-09-3)

Safety Data

• Hazardous Substances Data: 130293-09-3(Hazardous Substances Data)

Upstream product

• 114153-89-8 (4-Nitro-phenylsulfinamoyl)-acetic acid tert-butyl ester 
• 100-46-9 benzylamine 
• 119421-07-7 (3-Chloro-phenylsulfinamoyl)-acetic acid tert-butyl ester 
• 82185-52-2 t-butyl N-phenyl sulfinamoyl acetate 

Relevant articles and documents

Aminolysis of sulfinamoyl-esters, -sulfonamides and -sulfones. Thiooxamate and thiourea formation via a sulfine intermediate. Thiophilic or carbophilic reaction?

The aminolysis process of sulfinamoyl derivatives was investigated with sulfinamoyl esters. An intermediate sulfine was unambiguously evidenced by formation of a Diels-Alder type adduct. The aminolysis leads to final thiooxamate products. A carbophilic addition was suggested for the reaction with secondary amines. With sulfinamoyl, -sulfones and -sulfonamides, a thiourea is formed resulting from a double aminolysis.