130412-05-4

Basic information

• Product Name: S-Benzyl-N-methyl-thiohydroxylamine
• CAS NO: 130412-05-4
• Molecular Weight: 153.248
• Mol File: 130412-05-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: S-Benzyl-N-methyl-thiohydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: S-Benzyl-N-methyl-thiohydroxylamine(130412-05-4)
• EPA Substance Registry System: S-Benzyl-N-methyl-thiohydroxylamine(130412-05-4)

Safety Data

• Hazardous Substances Data: 130412-05-4(Hazardous Substances Data)

Upstream product

• 5601-23-0 3-(benzylthio)propanenitrile 

Relevant articles and documents

Alkyl- and Arylsulfenamides by Cyloelimination of Alkenes from Sulfimides, 3: Formation of Primary and Secondary Aliphatic Sulfenamides of Type RSNH2 or RSNHR1

N-Methyl- and N-unsubstituted alkansulfenamides 6, RSNHCH3 and RSNH2, without steric or electronic stabilization have been prepared by animation of 3-alkylthio-propionitriles or methyl 3-alkylthio-propanoates with O-mesitylenesulfonyl hydroxylamine or -N-methylhydroxylamine, deprotonation of the arising azasulfonium salts 3 and fast cycloelimination of acrylonitrile or methylacrylate from intermediarily formed N-methyl- or N-unsubstituted sulfimides 4.Sulfenamides 6 could be isolated as at least 90percent pure oily compounds and were characterized by spectral data (1H- and 13C-NMR, MS) and formation of sulfenimines 7 by condensation with benzaldehyde.