13051-65-5

Basic information

• Product Name: Benzene, 1-ethenyl-4-(methoxymethyl)-
• CAS NO: 13051-65-5
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 13051-65-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-ethenyl-4-(methoxymethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-ethenyl-4-(methoxymethyl)-(13051-65-5)
• EPA Substance Registry System: Benzene, 1-ethenyl-4-(methoxymethyl)-(13051-65-5)

Safety Data

• Hazardous Substances Data: 13051-65-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 53459-40-8 1-(2-chloroethyl)-4-(chloromethyl)benzene 
• 1592-20-7 4-Vinylbenzyl chloride 

Relevant articles and documents

Optimization of polystyrene-supported triphenylphosphine catalysts for aza-Morita-Baylis-Hillman reactions

A series of polar group functionalized polystyrene-supported phosphine reagents were examined as catalysts in the aza-Morita-Baylis-Hillman reactions of N-tosyl arylimines and a variety of Michael acceptors with the aim of identifying the optimal polymer/solvent combination. For these reactions JandaJel-PPh3 (1 mmol PPh3/g loading) resin containing methoxy groups (JJ-OMe-PPh3) on the polystyrene backbone in THF solvent provided the highest yield of all the catalyst/solvent combinations examined. The methyl ether groups were incorporated into JJ-OMe-PPh3 using commercially available 4-methoxystyrene, and thus such polar polystyrene resins are easily accessible and should find utility as nucleophilic catalyst supports.